Journal of Chemistry

STABILITY OF PHOSPHORIC P- MeO - PHENYLAMIDE DURING ACID HYDROLYSIS

Author & Affiliation:
Veena Singh (nee Sahni)
Department of Chemistry, Govt. P.G. College, Khandwa (INDIA)
Shashi Prabha
S.O.S., in Chemistry, Jiwaji University, Gwalior (INDIA)
Keyword:
PHENYLAMIDE DURING, ACID HYDROLYSIS
Issue Date:
December 2005
Abstract:

Hydrolysis of Phosphoric p-MeOptienylamide has been kinetically pursued in 0.01-7.0M, HCl media at 40°C (± 0.5). The Zwitterion (or the modified - Neutral) form functions at low acid (0.01 - 0.5M, HCl) molarities while the Neutral form makes an almost constant contribution between 1.0 to 4.0M, HCl. The Monoprotonated species, however, operates in the entire acid range (0.01 - 7.0M, HCl). Neutral electrolyte effect study also favours specific acid catalysis with a +ve ionic strength effect. Arrhenius Parameters’ determination, D2O effect and various correlations strengthen a bimolecular mode of hydrolysis in the entire acid region, leading to 3 mechanic routes in all.

Pages:
73-78
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
DOI:
juc

Copy the following to cite this article:

V. Singh; S. Prabha, "STABILITY OF PHOSPHORIC P- MeO - PHENYLAMIDE DURING ACID HYDROLYSIS", Journal of Ultra Chemistry, Volume 1, Issue 2, Page Number 73-78, 2018

Copy the following to cite this URL:

V. Singh; S. Prabha, "STABILITY OF PHOSPHORIC P- MeO - PHENYLAMIDE DURING ACID HYDROLYSIS", Journal of Ultra Chemistry, Volume 1, Issue 2, Page Number 73-78, 2018

Available from: http://www.journalofchemistry.org/paper/844/

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