Conductance behavior of Sodium, Potassium and Rubedium chlorides and Potassium bromide and iodide in 10%(W/W) 2-(ethoxy) ethanol – water mixture has been studied at 30o , 35o and 40oC. The equivalent conductance data have been analysed by making use of Fuoss-Kraus, Shedlovsky and Fuoss(1980) conductance equations to evaluate 0 and KA . There is a reasonable agreement between 0 and KA values obtained by Fuoss-Kraus and Sehdlovsky extrapolation techniques. But the values obtained by Fuoss (1980) equation are greater. An attempt is made to split 0 values of different electrolytes into ionic contribution. Different theories of ion-pair formation have been applied in order to evaluate the distance of closest approach. It is observed that all the theories exhibit their inability to predict the exact ion-association process. Walden products(00)are calculated to understand the solvation behavior.
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T. S. Murthy, "Conductance Studies of Alkali Metal Halides in 10%(W/W) 2-(Ethoxy) Ethanol-Water Mixture", Journal of Ultra Chemistry, Volume 15, Issue 3, Page Number 30-38, 2019Copy the following to cite this URL:
T. S. Murthy, "Conductance Studies of Alkali Metal Halides in 10%(W/W) 2-(Ethoxy) Ethanol-Water Mixture", Journal of Ultra Chemistry, Volume 15, Issue 3, Page Number 30-38, 2019Available from: http://www.journalofchemistry.org/paper/898/