Journal of Chemistry

Determination of stability constant and related thermodynamics of complex formation of Glutamic acid with some rare earth metals

Author & Affiliation:
Rajesh Kant Chaudhary
At+P.O.-Shubhankarpur, Darbhanga- 846004 (INDIA)
Anjani Kumar Mishra
M.R.M. College, Darbhanga
Prem Mohan Mishra
Department of Chemistry, M.L.S.M. College, Darbhaga, Bihar (INDIA)
Keyword:
Stability constant, pH metric method, Rare earth complexes, Glutamic acid ligand, Free energy change of complexation
Issue Date:
August 2009
Abstract:

In continuation of the previous work, practical proton ligand and metal ligand stability constants of the metal ions Y(III), Nd(III) and Pr(III) with glutamic acid ligand at temperature 203 K at constant ionic strength of 0.1 M KNO3 was determined. The stability constant was determined by the method of Bjerrum Calvin pH titration technique as adopted by Irving and Rossotti1-2. The stability constant of metal complexes with glutamic acid shows the sequence Y (III) > Nd(III) > Pr (III). Thermodynamic parameters such as free energy (DG), enthalpy charge (DH) and entropy charge DS also have been calculated.

 

Pages:
131-136
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
DOI:
juc

Copy the following to cite this article:

R. K. Chaudhary; A. K. Mishra; P. M. Mishra, "Determination of stability constant and related thermodynamics of complex formation of Glutamic acid with some rare earth metals", Journal of Ultra Chemistry, Volume 5, Issue 2, Page Number 131-136, 2018

Copy the following to cite this URL:

R. K. Chaudhary; A. K. Mishra; P. M. Mishra, "Determination of stability constant and related thermodynamics of complex formation of Glutamic acid with some rare earth metals", Journal of Ultra Chemistry, Volume 5, Issue 2, Page Number 131-136, 2018

Available from: http://www.journalofchemistry.org/paper/694/

Ansari Education And Research Society
Facebook Google Plus Twitter
Secured Site
Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License Cross Ref ACS