Comparison of conformation, spectral analysis and Biological activities of t-3-methyl-1-nitroso-r-2, c-6-diphenylpiperidin-4-one oxime and t- 3-isopropyl-1-nitroso-r-2, c-6- diphenylpiperidin-4-one oxime
1Department of Chemistry,A.V.C College (Autonomous), Mannampandal, Tamil Nadu India
2Department of Chemistry, IIT Gowahati Assam India
The comparison of t-3-methyl-1-nitroso-r-2,c-6-diphenylpiperidin-4-one oxime and t-3-isopropyl-1-nitroso-r-2,c-6-diphenylpiperidin-4 -one oxime. The effect of A1,3-stain introduced by N-NO group in N-nitroso 3-methyl-2,6-diphenylpiperidin-4-one and N-nitroso 3-isopropyl-2,6-diphenylpiperidin-4-one on the selectivity in the formation of oxime has been studied. The configurations and preferred conformations of the oximes of N-nitroso-2-6-dipheyl piperdin-4-ones have been determined using NMR spectral experiments and are found to prefer twist-boat conformation with equilibrium between two rotameric states due to restricted rotation around N- No bond.
Copy the following to cite this article:
N. Manivannan1, G. Selvanathan1, G. Murugavel2 and K. Amirthaganesan1 , "Comparison of conformation, spectral analysis and Biological activities of t-3-methyl-1-nitroso-r-2, c-6-diphenylpiperidin-4-one oxime and t- 3-isopropyl-1-nitroso-r-2, c-6- diphenylpiperidin-4-one oxime", Journal of Ultra Chemistry, Volume 7, Issue 1, Page Number 39-46, 2016Copy the following to cite this URL:
N. Manivannan1, G. Selvanathan1, G. Murugavel2 and K. Amirthaganesan1 , "Comparison of conformation, spectral analysis and Biological activities of t-3-methyl-1-nitroso-r-2, c-6-diphenylpiperidin-4-one oxime and t- 3-isopropyl-1-nitroso-r-2, c-6- diphenylpiperidin-4-one oxime", Journal of Ultra Chemistry, Volume 7, Issue 1, Page Number 39-46, 2016Available from: http://www.journalofchemistry.org/paper/462/
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