Organometallic Complexes of Rhodium (1) ligated by Heterocyclic Thioamides
1P.G. Centre of Chemistry (M.U.) College of Commerce Patna -800020 India
Ganga Devi Mahila Mahavidyalaya patna India
1Email:-rameshwarnath.pandey@yahoo.com
Organometallic derivatives of rhodium(1) of the type [RhX(P3)2(ligand)] (X = Cl-, Br-, NCS- & - SnCl3), [Rh X(P3) (CO)(ligand)] (X = Cl-/ Br-) and [Rh(P3)2)] (Py) (ligand)] BF4 have been synthesized using [Rh(P3)3] (X = Cl/ Br) as precursor and parachloro, paramethyl, paramethoxy and Para ethoxy derivatives of 1-phenyl tetrazoline-5thione as ligand. The oxidation state or rhodium in compounds was verified by titrating with cerric ammonium sulphate using ferroin as indicator. All four coordinated compounds are isostuctural with square planar precursor indicated by various physicochemical data.
Copy the following to cite this article:
R.N. PANDEY1* and PRAMILA SHARMA2, "Organometallic Complexes of Rhodium (1) ligated by Heterocyclic Thioamides", Journal of Ultra Chemistry, Volume 8, Issue 3, Page Number 341-346, 2016Copy the following to cite this URL:
R.N. PANDEY1* and PRAMILA SHARMA2, "Organometallic Complexes of Rhodium (1) ligated by Heterocyclic Thioamides", Journal of Ultra Chemistry, Volume 8, Issue 3, Page Number 341-346, 2016Available from: http://www.journalofchemistry.org/paper/428/
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License
