1Research Scholar
2Reader in Chemistry, C.M. Science College Darghanga India
3Professor in Chemistry MLSM College Darbhanga India
The kinetics and mechanism of Oxidation of glycollic acid with Bi(V) has been investigated in phosphoric acid medium.The order with respect to substrate and oxidant each is one. The reaction rate is independent of [H+] ion as well as [Bi (III) ]. The reaction rate decreases with increasing ionic strength indicating reactive species of opposite charge. The simple rate law explained all the experimental observations. The mode of electron transfer from the substrate to Bi(V) has been indicated is a bridged outer sphere mechanism.
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1MUKESH KUMAR JHA, 2AVINSH KUMAR, ASHOK KUMAR JHA and 3PREM MOHAN MISHRA*, "Kinetics and mechanism of oxidation of glycollic acid with Bi(V) in phosphoric acid medium", Journal of Ultra Chemistry, Volume 9, Issue 2, Page Number 257-264, 2016Copy the following to cite this URL:
1MUKESH KUMAR JHA, 2AVINSH KUMAR, ASHOK KUMAR JHA and 3PREM MOHAN MISHRA*, "Kinetics and mechanism of oxidation of glycollic acid with Bi(V) in phosphoric acid medium", Journal of Ultra Chemistry, Volume 9, Issue 2, Page Number 257-264, 2016Available from: http://www.journalofchemistry.org/paper/367/