Journal of Chemistry

Kinetics and mechanism of oxidation of glycollic acid with Bi(V) in phosphoric acid medium

Author:
1MUKESH KUMAR JHA, 2AVINSH KUMAR, ASHOK KUMAR JHA and 3PREM MOHAN MISHRA*
Affiliation:

1Research Scholar

2Reader in Chemistry, C.M. Science College Darghanga India

3Professor in Chemistry MLSM College Darbhanga India

Keyword:
Issue Date:
August 2013
Abstract:

The kinetics and mechanism of Oxidation of glycollic acid with Bi(V) has been investigated in phosphoric acid medium.The order with respect to substrate and oxidant each is one. The reaction rate is independent of [H+] ion as well as [Bi (III) ]. The reaction rate decreases with increasing ionic strength indicating reactive species of opposite charge. The simple rate law explained all the experimental observations. The mode of electron transfer from the substrate to Bi(V) has been indicated is a bridged outer sphere mechanism.

Pages:
257-264
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
DOI:
juc

Copy the following to cite this article:

1MUKESH KUMAR JHA, 2AVINSH KUMAR, ASHOK KUMAR JHA and 3PREM MOHAN MISHRA*, "Kinetics and mechanism of oxidation of glycollic acid with Bi(V) in phosphoric acid medium", Journal of Ultra Chemistry, Volume 9, Issue 2, Page Number 257-264, 2016

Copy the following to cite this URL:

1MUKESH KUMAR JHA, 2AVINSH KUMAR, ASHOK KUMAR JHA and 3PREM MOHAN MISHRA*, "Kinetics and mechanism of oxidation of glycollic acid with Bi(V) in phosphoric acid medium", Journal of Ultra Chemistry, Volume 9, Issue 2, Page Number 257-264, 2016

Available from: http://www.journalofchemistry.org/paper/367/

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