Journal of Chemistry

Mechanistic study of oxidation of mixture of Oxalic acid and Malonic acid by chromic acid in presence of Hydrochloric acid and its salts

Author:
JAIN VANDANA1 and ANSARI A.H2
Affiliation:

1Jai Narain College of Technology Bhopal India

2Bonnie Foi College Bhopal India

Email:- vipinvandana2002@yahoo.com

Keyword:
Issue Date:
April 2014
Abstract:

The oxidation of mixture of Oxalic acid + Malonic acid in presence of Hydrochloric acid in aqueous medium is reported here. The reaction is of first order with respect to each substrate; oxidant and [H+] The oxidation of mixture of acids was studied at different concentration of HCl. The products are CO2 and carbonyl di carboxylic acid. The rate constant increases with increase in concentration of added acid .The rate constant, catalytic constant, dielectric constant and effect of temperature were also determined. Various thermodynamic parameters like energy of activation, frequency factor were also determined. A mechanism consistent with result obtained has been proposed with the following rate equation:

Pages:
70-76
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
DOI:
juc

Copy the following to cite this article:

JAIN VANDANA1 and ANSARI A.H2, "Mechanistic study of oxidation of mixture of Oxalic acid and Malonic acid by chromic acid in presence of Hydrochloric acid and its salts", Journal of Ultra Chemistry, Volume 10, Issue 1, Page Number 70-76, 2016

Copy the following to cite this URL:

JAIN VANDANA1 and ANSARI A.H2, "Mechanistic study of oxidation of mixture of Oxalic acid and Malonic acid by chromic acid in presence of Hydrochloric acid and its salts", Journal of Ultra Chemistry, Volume 10, Issue 1, Page Number 70-76, 2016

Available from: http://www.journalofchemistry.org/paper/307/

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