Synthesis and Spectroscopic Characterization of Seven-Coordinate Complexes of Niobium (V) and Tantalum (V) with Dibenzyl Sulphide
Author:
R.N. PANDEY* and K.V. GAUTAM
Affiliation:
P.G. Centre of Chemistry (M.U.) College of Commerce Patna India
Email: rameshwarnath.pandey@yahoo.com
Keyword:
Issue Date:
April 2014
Abstract:
Dibenzyl sulphide forms stable complexes of composition [MX5(R2S)] (M=Nb/Ta; X=Cl/Br; R=C6H5CH2) and [NbOX3(R2S)2] (X = Cl/ Br; R = C6H5CH2). The compositions of the complexes have been established by elemental analysis, magnetic susceptibility measurements, conductivity, IR, UV-vis and 1H NMR spectral data. These complexes are seven-coordinate and halogen-bridged or oxygen-bridged pentagonalpyramidal dimeric structure.
Pages:
19-24
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
DOI:
juc
Copy the following to cite this article:
R.N. PANDEY* and K.V. GAUTAM, "Synthesis and Spectroscopic Characterization of Seven-Coordinate Complexes of Niobium (V) and Tantalum (V) with Dibenzyl Sulphide", Journal of Ultra Chemistry, Volume 10, Issue 1, Page Number 19-24, 2016Copy the following to cite this URL:
R.N. PANDEY* and K.V. GAUTAM, "Synthesis and Spectroscopic Characterization of Seven-Coordinate Complexes of Niobium (V) and Tantalum (V) with Dibenzyl Sulphide", Journal of Ultra Chemistry, Volume 10, Issue 1, Page Number 19-24, 2016Available from: http://www.journalofchemistry.org/paper/302/
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