Journal of Chemistry

Polarographic study of mixed-ligand complexes of In (III) with Citrulline and Hippuric acid at different Temperatures

Author & Affiliation:
Santosh Kumar
Department og Chemistry, Universtiy of Rajasthan, Jaipur- 3022055 (INDIA)
O.D. GUPTA (gupata-od@yahoo.com)
Department og Chemistry, Universtiy of Rajasthan, Jaipur- 3022055 (INDIA)
Keyword:
mixed-ligand complexes
Issue Date:
December 2010
Abstract:

In (III) has been investigated with Citrulline and Hippuric acid as mixed-ligand complexes at dropping mercury electrode by the polarographic technique. The stability constants of In(III)-Citrulline and In(III)-Hippuric acid were determined first by the DeFord and Hume's method. Later the In(III) was studied with mixed-ligand Citrulline and Hippuric acid by the Schaaf and McMaster's method. The reduction of all mixed-ligand complexes has been found to be quasirreversible and diffusion controlled. Three species of mixed-ligand complexes MXY, MX2Y and MXY2 have been determined and found to be more stable than that of simple complexes. The detailed temperature effect has been also studied.

Pages:
253-258
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
DOI:
juc

Copy the following to cite this article:

S. Kumar; O. Gupta, "Polarographic study of mixed-ligand complexes of In (III) with Citrulline and Hippuric acid at different Temperatures ", Journal of Ultra Chemistry, Volume 6, Issue 3, Page Number 253-258 , 2018

Copy the following to cite this URL:

S. Kumar; O. Gupta, "Polarographic study of mixed-ligand complexes of In (III) with Citrulline and Hippuric acid at different Temperatures ", Journal of Ultra Chemistry, Volume 6, Issue 3, Page Number 253-258 , 2018

Available from: http://www.journalofchemistry.org/paper/582/

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