Mixed Ligand Complexes of Cd(II) Ion with Adipic acid and some Bicarboxylic Acids at DME
Department of Chemistry,University of Rajasthan Jaipur-302004 India
Email:-chandelcps2@rediffmail.com
The stability constant of mixed ligand complexes of Cd(II) with adipic acid and some bicarboxylic acids (Malonic Acid, L(+)Tartaric Acid, DLMalic Acid, Maleic Acid and Succinic Acid) have been determined electrochemically. The stepwise formation constants of simple CdAdipic acid and CdBicarboxylic acids have been investigated by Deford and Hume's method. Then the mixed ligand complexes of Cd with adipic acid and bicarboxylic acids have been studied by the method of Schaap & McMasters. The mixing constant (KM) and stabilization constant (KS) were measured for the comparison of the simple and mixed ligand complexes. The positive value of mixing constants and stabilization constants show that the ternary complexes are more stable than the binary complexes.
Copy the following to cite this article:
Trapti Gupta and C. P. Singh Chandel* , "Mixed Ligand Complexes of Cd(II) Ion with Adipic acid and some Bicarboxylic Acids at DME ", Journal of Ultra Chemistry, Volume 7, Issue 3, Page Number 439-458, 2016Copy the following to cite this URL:
Trapti Gupta and C. P. Singh Chandel* , "Mixed Ligand Complexes of Cd(II) Ion with Adipic acid and some Bicarboxylic Acids at DME ", Journal of Ultra Chemistry, Volume 7, Issue 3, Page Number 439-458, 2016Available from: http://www.journalofchemistry.org/paper/525/
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License
