Journal of Chemistry

An Electroanalytical study of Complexes of Cd(II) with Para Aminohippuric Acid(PAHA) and Some Bicarboxylic Acids at DME

Author:
Trapti Gupta and C. P. Singh Chandel*
Affiliation:

Department of Chemistry, University of Rajasthan Jaipur India

Email:-chandelcps2@rediffmail.com

Keyword:
Para Aminohippuric Acid (PAHA), Bicarboxylic Acids, Stability Constants.
Issue Date:
December 2011
Abstract:

The stability constant of mixed ligand complexes of Cd(II) with para aminohippuric acid and some bicarboxylic acids (Malonic Acid, L(+)Tartaric Acid, DLMalic Acid, Maleic Acid and Succinic Acid) have been determined electrochemically. The stepwise formation constants of simple Cd para aminohippuric acid and Cdbicarboxylic acids have been investigated by Deford and Hume's method. Then the mixed ligand complexes of Cd with PAHA and bicarboxylic acids have been studied by the method of Schaap & McMasters. The mixing constant (KM) and stabilization constant (KS) were measured for the comparison of the simple and mixed ligand complexes. The positive value of mixing constants and stabilization constants show that the ternary complexes are more stable than the binary complexes. 
 

Pages:
369-384
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
DOI:
juc

Copy the following to cite this article:

Trapti Gupta and C. P. Singh Chandel* , "An Electroanalytical study of Complexes of Cd(II) with Para Aminohippuric Acid(PAHA) and Some Bicarboxylic Acids at DME ", Journal of Ultra Chemistry, Volume 7, Issue 3, Page Number 369-384, 2016

Copy the following to cite this URL:

Trapti Gupta and C. P. Singh Chandel* , "An Electroanalytical study of Complexes of Cd(II) with Para Aminohippuric Acid(PAHA) and Some Bicarboxylic Acids at DME ", Journal of Ultra Chemistry, Volume 7, Issue 3, Page Number 369-384, 2016

Available from: http://www.journalofchemistry.org/paper/516/

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