A Kinetics study of miceller catalyzed oxidation of acetic acid by acidic permanganate
Department of Chemistry Govt. Autonomous Holkar Science College Indore India
Email:- vandana203@gmail.com
A kinetic study of oxidation of acetic acid has been investigated in presence and absence of anionic micelle; sodium lauryl sulphate (NaLS). The reaction is a double stage process, in which first stage is followed by second fast stage process. It is observed that the rate was increased in the presence of surfactant. A first order kinetics is observed with respect to substrate and oxidant. The data has been examined in the light of Zucker - Hammett, Bunnett and Bunnett-Olsen criteria of reaction mechanism. The stiochiometry was observed to be in terms of mole ratio of permanganate ion and acetic acid consumed. Effect of specific ion on the reaction rate has also been reported. Activation parameters for the reaction are evaluated and the plausible mechanism is suggested.
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VANDANA SHARMA* and VIJAY R. CHOUREY1, "A Kinetics study of miceller catalyzed oxidation of acetic acid by acidic permanganate", Journal of Ultra Chemistry, Volume 9, Issue 3, Page Number 287-302, 2016Copy the following to cite this URL:
VANDANA SHARMA* and VIJAY R. CHOUREY1, "A Kinetics study of miceller catalyzed oxidation of acetic acid by acidic permanganate", Journal of Ultra Chemistry, Volume 9, Issue 3, Page Number 287-302, 2016Available from: http://www.journalofchemistry.org/paper/371/
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