Journal of Chemistry

Electrochemical behavior of copper ion on N-methyl piperazine substituted organic compound modified Wax Impregnated Graphite Electrode

Author:
N. RAMALAKSHMI* and B. MARICHAMY
Affiliation:

Post Graduate and Research Department of Chemistry, Presidency Collge (Autonomous), Chennai (INDIA)
Email:-*rrama_subhar@yahoo.co.in

Keyword:
electrochemical impedance spectroscopy, cyclic voltammtry, copper redox system, interference study, sensor
Issue Date:
April 2012
Abstract:

Fabrication of 2, 5 bis (4-methyl piperaz-1yl-methyl) 1-4- hydroquinone modified Wax Impregnated Graphite Electrode (WIGE) was used for highly selective, sensitive accumulation and detection of copper ions in real samples. Techniques like cyclic voltammetry(CV) and electrochemical impedance spectroscopy(EIS) were used to investigate ligand modified WIGE and the ion permeation through it. The electrochemical behavior of copper ions on ligand modified WIGE was studied through scan rate effect and pH study. The results indicated that CV peak currents have a linear relationship with concentration in the range of 0.05mM to 5mM, with a correlation coefficient of 0.983. The detection limit could be estimated 5 x 10-5M for Cu(II) ion by cyclic voltammetric method. The interference study was performed for equal molar concentrations of Cu(II), Pb(II) and Hg(II) ions on ligand modified WIGE.

Pages:
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
DOI:

Copy the following to cite this article:

N. RAMALAKSHMI* and B. MARICHAMY, "Electrochemical behavior of copper ion on N-methyl piperazine substituted organic compound modified Wax Impregnated Graphite Electrode", Journal of Ultra Chemistry, Volume 8, Issue 1, Page Number , 2016

Copy the following to cite this URL:

N. RAMALAKSHMI* and B. MARICHAMY, "Electrochemical behavior of copper ion on N-methyl piperazine substituted organic compound modified Wax Impregnated Graphite Electrode", Journal of Ultra Chemistry, Volume 8, Issue 1, Page Number , 2016

Available from: http://www.journalofchemistry.org/paper/353/

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